Rui Toscano has exhibited in institutions and galleries such as the José de Guimarães International Arts Centre (Guimarães), the National Museum of Contemporary Art – Museu do Chiado (Lisbon), the Museu de Serralves (Porto), Cristina Guerra Contemporary Art (Lisbon), Culturgest (Lisbon); MEIAC (Badajoz), among others. In 2009, he designed the exhibition The Great Curve for the Chiado 8 space
His works are represented in the collections of the Modern Art Centre of the Gulbenkian Foundation, Caixa Geral de Depósitos, the Luso-American Development Foundation and PLMJ, among others.